Our group's research interests have focused for many years on the general field of Supramolecular Electrochemistry.1 Our work in the field of molecular self-assembly has been highly visible, as noted by ISI Essential Science Indicators. Specifically, we have used redox processes to control the structure and properties of supramolecular aggregates, such as host-guest complexes and other more complicated assemblies.2 We have also investigated supramolecular effects on the thermodynamics and kinetics of electron-transfer reactions.3 Currently, our work focuses on the investigation of similar supramolecular phenomena involving nanometer-sized host and guest species, such as metal nanoparticales and/or dendrimers. Specific projects are listed below: Metal Nanoparticles Modified with Molecular Receptors Electroactive and Fluorescent Dendrimers Synthesis and Characterization of New Hosts Funding

This book describes the electrochemical behavior of supramolecular systems. Special emphasis is given to the electrochemistry of host-guest complexes, monolayer and multilayer assemblies, dendrimers, and other supramolecular assemblies. A fundamental theme throughout the book is to explore the effects that supramolecular structure exerts on the thermodynamics and kinetics of electrochemical reactions. Conversely, attention will be placed to the various ways in which electrochemical or redox conversions can be utilized to control or affect the structure or properties of supramolecular systems. This first book on this topic will be of value to graduate students and advanced researchers in both electrochemistry and supramolecular chemistry.

References: 1Kaifer, A. E.; Gómez-Kaifer, M. Supramolecular Electrochemistry, Wiley-VCH: Weinheim, 1999. 2Kaifer, A. E. "The Interplay Between Molecular Recognition and Redox Chemistry" Acc. Chem. Res. 1999, 32, 62-71. 3Cardona, C. M.; Mendoza, S.; Kaifer, A. E. "Electrochemistry of Encapsulated Redox Centers", Chem. Soc. Rev. 2000, 29, 37-42